Theoretical calculation of equilibrium Mg isotope fractionation between silicate melt and its vapor     

Haiyang Luo  Huiming Bao  Yuhong Yang  Yun Liu 《中国地球化学学报》2018,37(5):655-662

Isotope fractionation during the evaporation of silicate melt and condensation of vapor has been widely used to explain various isotope signals observed in lunar soils, cosmic spherules, calcium–aluminum-rich inclusions, and bulk compositions of planetary materials. During evaporation and condensation, the equilibrium isotope fractionation factor (α) between high-temperature silicate melt and vapor is a fundamental parameter that can constrain the melt’s isotopic compositions. However, equilibrium α is difficult to calibrate experimentally. Here we used Mg as an example and calculated equilibrium Mg isotope fractionation in MgSiO₃ and Mg₂SiO₄ melt–vapor systems based on first-principles molecular dynamics and the high-temperature approximation of the Bigeleisen–Mayer equation. We found that, at 2500 K, δ²⁵Mg values in the MgSiO₃ and Mg₂SiO₄ melts were 0.141?±?0.004 and 0.143?±?0.003‰ more positive than in their respective vapors. The corresponding δ²⁶Mg values were 0.270?±?0.008 and 0.274?±?0.006‰ more positive than in vapors, respectively. The general \(\alpha - T\) equations describing the equilibrium Mg α in MgSiO₃ and Mg₂SiO₄ melt–vapor systems were: \(\alpha_{{{\text{Mg}}\left( {\text{l}} \right) - {\text{Mg}}\left( {\text{g}} \right)}} = 1 + \frac{{5.264 \times 10^{5} }}{{T^{2} }}\left( {\frac{1}{m} - \frac{1}{{m^{\prime}}}} \right)\) and \(\alpha_{{{\text{Mg}}\left( {\text{l}} \right) - {\text{Mg}}\left( {\text{g}} \right)}} = 1 + \frac{{5.340 \times 10^{5} }}{{T^{2} }}\left( {\frac{1}{m} - \frac{1}{{m^{\prime}}}} \right)\), respectively, where m is the mass of light isotope ²⁴Mg and m′ is the mass of the heavier isotope, ²⁵Mg or ²⁶Mg. These results offer a necessary parameter for mechanistic understanding of Mg isotope fractionation during evaporation and condensation that commonly occurs during the early stages of planetary formation and evolution.  相似文献   

赫南特冰期古海洋环境转变及其成因机制研究现状     

杨向荣  严德天  张利伟  张宝  徐翰文  刘文慧  郧嘉琳 《沉积学报》2018,36(2):319-332

奥陶纪-志留纪转折期是地质历史时期一个重要的时间节点,形成了广为人知的赫南特冰期。该冰期的形成不仅诱发了显生宙第二大的两幕生物绝灭事件,同样使海水中的地球化学元素循环受到强烈的影响,如海洋碳酸盐与大气CO₂的循环受到扰动,全球海平面的降低促使水体逐渐富氧化,进而导致海洋水体Mo、S、U等同位素值出现波动,而冈瓦纳大陆被冰雪大面积覆盖则削弱了铝硅酸盐岩的风化作用,并限制了陆壳放射性187Os、87Sr同位素向海水的运移。赫南特冰期的成因一直是学界探讨的热点,被归结于风化作用、火山活动的增强或有机碳的大量埋藏等因素,但对冰期的成因机制与持续时间仍具有较多的争论,其原因很多,比如缺乏独立的生物地层单元同时能够控制浅水碳酸盐岩及深水泥页岩区,缺少转折界限处高精度的地球化学信息与全球等时地层格架下的对比,以及未能排除风化作用、成岩作用和构造热事件对古海洋与古气候重建时的扰动等。  相似文献   

Sinian-Cambrian Tectonic Framework in the Tarim Basin and its Influences on the Paleogeography of the Early CambrianEI北大核心CSCD     

Yan W.  Wu G.  Zhang Y.  Yang G.  Lou H.  Wang X. 《大地构造与成矿学》2018,(3):455-466

Due to strong remodification and sparse trace remnants, tectonic restoration is critical for the reconstructing of the paleography and basin-prototype in the multiple-cycles superimposed basin, which is also fundamental for the hydrocarbon exploration of the deep marine carbonate in the Tarim Basin. This study presents the tectonic framework of the transition phase from the Sinian to the Cambrian Period and its constrains on the paleography of the Cambrian in the Tarim Basin based on comprehensive analysis of new geochronology data, seismic data and regional tectonic data. The results showed that (1) there is a large regional unconformity between the Cambrian and Precambrian, suggesting a discontinuous deposition from the Sinian to the Cambrian that is contrary to the major view; (2) a broad flattened paleotopography formed before Cambrian Period, which is favorable for the wide epicontinental sea environment and a gentle homoclinal ramp platform development in the early Cambrian, and the residual basement low relief uplifts that influence the microfacies differentiation in the carbonate platform; (3) the Cambrian carbonate platform has been involved much into the marginal orogenic belts, and the proto-platform is probably of 200 km out of the present basin in S-N direction; (4) there is a weak extensional setting in the Cambrian-Early Ordovician rather than a strong rifting setting with a large aulacogen into the platform, in which a inter-platform shallow depression and stable ramp platform developed in the Cambrian; (5) there is not troughs, but rather low relief uplifts developed in the Early Cambrian in the southwestern Tarim Basin, and lack of large uplifts along the carbonate platform margins; (6) it is showed a broad architecture of platform-wide slope-ocean basin from the inner Tarim plate to its margin in the Cambrian Period. Considering the basin prototype, the restoration of the tectono-paleography in the early Cambrian in the Tarim Basin is distinct from those of the previously proposed. We propose that a gentle pattern with “two platforms and one inter-depression” in E-W striking other than multiple small platform constrained in the basin, and further subdivision of the western platform with inner platform low uplift and sag in N-S striking, which is possibly inherited from the basement architecture. On the outer of the united platform, there is probably broad gentle slope for transition to ocean basin. We therefore argue that tectonic restoration is crucial for reconstruction of the paleogeography and basin prototype, especially for basins experienced multiphase of tectonic cycles. © 2018, Science Press. All right reserved.  相似文献   

Hydrothermal Dolomite: A Review and PerspectiveEI北大核心CSCD     

Li Q.  Bao Z. 《大地构造与成矿学》2018,(4):699-717

Hydrothermal dolomite commonly closely associates with oil-gas reservoirs and sediment-hosted Pb-Zn deposits, the Mississippi Valley-type (MVT) Pb-Zn deposits in particular. Host rocks of MVT deposits usually experienced extensive dolomitization, and indeed, hydrothermal dolomite is considered as a useful prospective indicator for MVT mineralization. However, genetic link between the hydrothermal dolomitization and MVT Pb-Zn mineralization is a matter of debate. This paper briefly reviewed the nomenclature and research history of hydrothermal dolomite, introduced the major geological, geochemical characteristics, and distribution of hydrothermal dolomite, spatial and possibly genetic relationship between hdyrothermal dolomite and hdyrothermal ore deposits and oil-gas reservoirs based on case studies including the occurrence of hydrothermal dolomites in MVT deposits in Southwest China. The temporal and genetic relationships between dolomitizaiton and thermal sulfate reduction, sulfide precipitation and thus the location of ore mineralization well worthy more attention, and comprehensive geological and isotope geochemical and state of art in situ techniques will contribute to understanding of the genesis of hydrotherml dolomite and the spatially related ore deposits and oil-gas reservoirs. © 2018, Science Press. All right reserved.  相似文献   

黑河流域乡镇初始水权分配研究——以甘州区为例     

王鹏龙  宋晓谕  王宝  王肖波  牛艺博 《冰川冻土》2021,43(4):1218-1227

乡镇水权分配是乡镇水资源承载力研究的前提,是乡镇落实最严格的水资源管理和水权交易制度的基础,为新时期乡村振兴与美丽乡村建设提供物质保障。以最严格水资源管理制度确定的甘州区用水总量控制目标为可分配水权总量,在优先保障生活和生态基本用水基础上,选取2017年为规划水平年,采用人口、面积、产值单指标和混合分配模式,以及综合指标分配模式5种方法,开展了乡镇尺度水权分配对比研究。结果表明：领域专家对水权分配的公平性的重视程度略大于效率性,区域水资源的管理者更注重水权分配的公平性,而研究学者更倾向于效率性。5种模式对同一乡镇的水权分配结果范围较为均衡,但不同模式因侧重点各异对具体乡镇的分配比例存在差异。各乡镇不同模式下最大水权分配比例处于10%以上,而最小比例不超过0.3%。基于AHP的综合指标模式的分配结果更为合理,更贴合各乡镇水资源利用现状与经济社会未来发展潜力,其分配结果为各乡镇水资源承载力研究奠定了基础。  相似文献   

河北围场早白垩世鲎虫化石性双形现象研究     

包彩凤 《江苏地质》2021,45(2):143-149

对产自河北围场下白垩统九佛堂组的65件鲎虫化石标本进行研究。根据其形态特征,认为这些鲎虫化石属于三角围场鲎虫（Weichangiops triangularisYang et Hong, 1980）。有观点认为,具有上肛板的鲎虫为冷水型鲎虫,而不具上肛板的鲎虫为暖水型鲎虫。河北围场采集的鲎虫化石有的具上肛板,有的不具上肛板,目前没有任何证据表明其为冷水型鲎虫与暖水型鲎虫混生的产物。通过研究,对三角围场鲎虫的特征进行了适当修正,认为围场地区的鲎虫化石具1对复眼,因此依据单个复眼而建立的新亚科——围场鲎虫亚科（Weichangiopsinae）不成立,应予以摒弃。三角围场鲎虫存在明显的性双形现象,雄性个体尾部具有上肛板,雌性个体不具有上肛板,这对于鲎虫化石分类研究具有重要的科学价值,可避免在生物分类时发生同物异名现象。  相似文献   

河南省人工防雹作业指挥系统研发及应用     

鲍向东  丁建芳  杜春丽  刘磊  郭丽梅 《气象与环境科学》2019,42(1):127-134

利用河南省历史气象资料,结合先进的防雹理论与技术,系统分析和总结了河南省冰雹过程的天气尺度与中尺度概念模型,并根据三维冰雹云数值模式及雷达探测、闪电定位、卫星、自动站数据,研发出河南省人工防雹作业指挥系统。该系统包括天气形势分析子系统和作业决策指挥子系统。天气形势分析子系统可根据大尺度形势背景、中尺度系统特征及三维冰雹云数值模式和卫星、闪电、自动站资料,对可能降雹区进行预测。作业决策指挥子系统通过对雷达数据产品的二次开发,完成雷达资料处理、产品生成及风暴自动识别、分类、预警,并根据参数的变化和雹云的移动方向,对下游作业区进行预警及输出作业方案。整个系统基于VS2005开发平台,使用c++开发语言,利用图层分层管理将地理信息、雷达实时观测资料、雷达二次产品、高空资料、火箭和高炮作业点等信息分层显示。系统自动化程度高,操作简便,为河南省冰雹天气预报预警提供了可参考的技术指标体系。  相似文献   

DYYZ-Ⅱ型自动气象站测温故障排除方法与思路     

赵建凯  安学武  贾成朕  包伟智  李博 《内蒙古气象》2019,(1):46-48

文章通过DYYZ-Ⅱ型自动气象站出现的一次气温、地温数据缺测故障,分析了DYYZ-Ⅱ型自动气象站出现测温故障时的故障排除过程与排除思路,为保障技术人员在处理此类故障时提供了方法和依据。  相似文献   

吸湿性播撒对暖性对流云减雨影响的数值模拟          下载免费PDF全文

刘佩  银燕  陈倩  楼小凤 《应用气象学报》2019,30(2):211-222

利用以色列特拉维夫大学二维面对称分档云模式（two-dimensional slab-symmetric detailed spectral bin microphysical model of Tel Aviv University）,对2016年9月4日16:00（北京时）前后我国华东地区的一次暖性浅对流云降水过程进行模拟,模式模拟的强回波中心高度和最大回波强度范围与观测基本一致。并在此基础上进行了小于1 μm的吸湿性核的播撒减雨试验,分别考虑了不同播撒时间、不同播撒高度以及不同播撒剂量的敏感性测试。结果表明:在云的发展阶段早期播撒能起到更好的减雨效果,播撒时间越早对大粒子生长过程的抑制作用越强,随着播撒时间向后推移,受抑制作用最显著的粒径段向小粒径端偏移;在云中心过饱和度大的区域下方进行播撒,减雨效果更加明显,当播撒剂量为350 cm-3时,地面累积降水量减少率可达23.3%;另外,随着播撒剂量的增加,减雨效果更加显著,甚至能达到消雨的效果。因此,在暖性浅对流云中合理地播撒小于1 μm的吸湿性核能达到较好的减雨或消雨效果。  相似文献   

南北两极海冰的涛动关系          下载免费PDF全文

解思梅  包澄澜  郝春江 《极地研究》1994,6(3):41-55

本文将南极海冰分为４个区：ＳＰＩ１（０°－１２０°Ｅ），东南极海冰；ＳＰＩ２（１２０°Ｅ－１２０°Ｗ），以罗斯海为主体的海冰区；ＳＰＩ３（１２０°Ｗ－０°），以威德尔海为主体的海冰区；ＳＰＩ４，全南极海冰区。北极海冰区分为３个区：ＮＰＩ１（９０°Ｅ－１８０°－９０°Ｗ），太平洋侧冰区；ＮＰＩ２（９０°Ｗ－０°－９０°Ｅ），大西洋侧冰区；ＮＰＩ３，全北极冰区。本文使用了ＷＤＣ－Ａ的ＳＩＧＲＩＤ海冰资料，以分析南极和北极各冰区之间的相互关系。发现两极各冰区之间存在着非常复杂的相互作用。其中最突出的特征是：两极海冰之间相互作用的振源是ＮＰＩ２。ＳＰＩ３是影响南极海冰的正反馈中心。ＳＰＩ２则是南北两极海冰的负反馈中心。ＮＰＩ２，ＳＰＩ３和ＳＰＩ２之间的相互作用最强，形成涛动关系。这种涛动关系不是同时期的，而是有较长的滞后时间差。两极海冰形成周期变化，其周期为５－６年，正与ＮＰＩ２和ＳＰＩ３自身变化周期一致。另外还有更长的循环周期９－１１年  相似文献